2,3,4-Tri-O-acetyl-β-l-arabinopyranosyl trichloroacetimidate
نویسنده
چکیده
In the title compound, C(13)H(16)Cl(3)NO(8), the trichloro-acetimidate group is located in an axial postion on the anomeric carbon of the sugar ring.
منابع مشابه
Palladium-charcoal-catalyzed reduction of tri-O-acetyl-beta-L-fucopyranosyl cyanide: a route to small cluster oligosaccharide mimetics (SCOMs).
[reaction: see text] Synthesis of glycosyl cyanides was optimized with a new catalyst system. Reduction of tri-O-acetyl-beta-L-fucopyranosyl cyanide with Pd-hydrogen, in the presence of Ac(2)O and Boc(2)O, gave N-protected-mono- and -di-(2,3,4-tri-O-acetyl-beta-L-fucopyranosylmethyl)-amines, which allow for the syntheses of small cluster oligosaccharide mimetics of fucopyranosylomethyl-substitu...
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